一、主持科研项目情况: (1) 国家自然科学基金青年科学基金项目(C类),22501234,2026-2028,主持 (2) 湖南省教育厅重点项目,24A0112,2024-2026,主持 (3) 湖南省自然科学基金青年基金项目,2023JJ40620,2023-2025,主持 (4) 广东省基础与应用基础研究基金项目,2022A1515110984,2022-2025,主持 (5) 湘潭大学科研启动项目,22QDZ16,2022-2025,主持 (6) 广州市基础研究计划基础与应用基础研究项目,202102020964,2021-2023,主持 (7) 中国博士后科学基金特别资助(站前)项目,2020TQ0100,2020-2021,主持 (8) 中国博士后科学基金面上资助项目,2019M662890,2019-2021,主持 二、发表学术论文情况(第一/通讯作者): (1) Wang, S.; Lai, T.; Li, H.*; Zhao, J.*; Zhang, G., Organocatalytic Alternating Copolymerization of Isothiocyanate and Trifluoropropylene Oxide: Fluorine-Enhanced Polymerizability and Depolymerizability. Macromol. Rapid Commun. 2025, e00875. (2) Li, H.; Zeng, W.; Li, Z.; Zhao, J.*; Zhang, G., One-Step Hybrid Block Copolymerization by Organocatalysis. Prog. Polym. Sci. 2025, 163, 101955. (3) Li, J.; Guan, Y.; Hao, T.-T.; Huang, J.; Chen, Y.; Li, H.*; Duan, P.*; Xie, H.-L.*, Phosphorescent Liquid Crystalline Polymer-Based Circularly Polarized Luminescence Optical Waveguides for Enhanced Photonic Signal Processing and Information Encryption. Angew. Chem. Int. Ed. 2025, 64, e202423395. (4) Zhao, C.#; He, G.#; Chen, T.; Li, H.*; Zhao, J.*, Precision Organocatalytic Synthesis of Fluoropolyesters with Enhanced Degradability and Ionic Conductivity. Macromolecules 2025, 58, 1630-1641. (5) Li, J.; Hao, T.-T.; Chen, J.-K.; Huang, J.; Chen, Y.; Cai, J.-H.; Guan, Y.*; Li, H.*; Xie, H.-L.*, Fluorescence and Phosphorescence Dual-Emission Liquid Crystal Polymer Optical Waveguide for Logical Gate. Chem. Asian J. 2025, 20, e202401563. (6) Chen Y.; Li Z.; Guan Y.; Huang J.; Li J.; Qi J.; Wu M.; Li, H.*; Xie, H.-L.*, Tunable Circularly Polarized Luminescence from Polyether-Based Liquid Crystalline Polymer. Macromol. Chem. Phys. 2025, 226, 2500084. (7) Liu, L.#; Li, H.#; Zhang, P.; Zhou, Y.; Zhao, J.*; Zhang, G.*, Hybrid Anionic Block Copolymerization: From Organocatalysis-Streamlined Crossover to Internally Microphase-Separated Aggregates. Aggregate 2024, 5, e541. (8) Li, Y.; Li, Z.; Zeng, W.; Shen, Y.; Fang, Y.; Wang, Y.*; Li, H.*, Synthesis of Alternating Polyesters Using a Dual Catalytic System of Alkali Metal Alkoxides and Crown Ether. Eur. Polym. J. 2024, 220, 113497. (9) He, X.; Pang, J.; Li, H.*; Zhao, J.*, Synthesis of Bio-Based Polyesters from Carvone-Derived Epoxides. Eur. Polym. J. 2024, 203, 112669. (10) Huang, Y.; Zhao, C.; Zhang, B.; Li, H.*; Zhao, J.*, Marriage of Organic and Grubbs Catalysts for Tandem Synthesis of Bottlebrush Polyesters. ACS Macro Lett. 2023, 12, 1711-1717. (11) 何冠辰; 高生辉; 李恒*; 赵俊鹏*, 杂化嵌段共聚物的无金属催化一步合成. 中国材料进展 2023, 42, 441-455. (12) Zdovc, B.#; Li, H.#; Zhao, J.*; Pahovnik, D.; Žagar, E.*, Influence of Microstructure on the Elution Behavior of Gradient Copolymers in Different Modes of Liquid Interaction Chromatography. Anal. Chem. 2022, 94, 7844-7852. (13) Hu, S.; Liu, L.; Li, H.*; Pahovnik, D.; Hadjichristidis, N.; Zhou, X.; Zhao, J.*, Tuning the Properties of Ester-Based Degradable Polymers by Inserting Epoxides into Poly(ε-caprolactone). Chem. Asian J. 2022, 18, e202201097. (14) He, G.; Li, H.*; Zhao, J.*, One-Step Sequence-Selective Synthesis of Block Copolyester from Mixed Phthalic Anhydride, Cyclohexene Oxide, and δ-Valerolactone. Macromol. Chem. Phys. 2022, 223, 2100321. (15) Li, H.; He, G.; Chen, Y.; Zhao, J.*; Zhang, G., One-Step Approach to Polyester–Polyether Block Copolymers Using Highly Tunable Bicomponent Catalyst. ACS Macro Lett. 2019, 8, 973-978. (16) Li, H.; Luo, H.; Zhao, J.*; Zhang, G., Sequence-Selective Terpolymerization from Monomer Mixtures Using a Simple Organocatalyst. ACS Macro Lett. 2018, 7, 1420-1425. (17) Li, H.; Luo, H.; Zhao, J.*; Zhang, G., Well-Defined and Structurally Diverse Aromatic Alternating Polyesters Synthesized by Simple Phosphazene Catalysis. Macromolecules 2018, 51, 2247-2257. (18) Li, H.; Zhao, J.*; Zhang, G., Self-Buffering Organocatalysis Tailoring Alternating Polyester. ACS Macro Lett. 2017, 6, 1094-1098. (19) Li, H.; Liu, P.; Yuan, J.; Si, J.; Liu, Y.; Li, H.; Gao, Y.*, Thermo-Responsive Brush Copolymers by “Grafting through” Strategy Implemented on the Surface of the Macromonomer Micelles and Their High Emulsifying Performance. Macromol. Chem. Phys. 2017, 218, 1700131. (20) Li, H.; Miao, H.; Gao, Y.*; Li, H.; Chen, D., Efficient Synthesis of Narrowly Dispersed Amphiphilic Double-Brush Copolymers through the Polymerization Reaction of Macromonomer Micelle Emulsifiers at the Oil-Water Interface. Polym. Chem. 2016, 7, 4476-4485. (21) Li, H.; Yang, D.; Gao, Y.*; Li, H.; Xu, J.*, Dual Responsive Macroemulsion Stabilized by Y-Shaped Amphiphilic AB2 Miktoarm Star Copolymers. RSC Adv. 2015, 5, 96377-96386. 三、申请专利情况: (1) 赵俊鹏,李恒,何冠辰,张广照. 一种烯烃和环氧化物嵌段共聚的方法,中国发明专利,授权号:ZL202110261669.6 (2) 赵俊鹏,李恒,张广照. 一种苯酐与环氧化合物共聚及序列控制方法,中国发明专利,授权号:ZL201910004325.X (3) 赵俊鹏,庞杰,李恒. 一种主链缩醛官能化共聚物的制备方法,中国发明专利,授权号:ZL202110960870.3 (4) 高勇,袁俊,李恒,杨端光,黎华明. 一种聚氨酯接枝共聚物及其制备方法,中国发明专利,授权号:ZL201510575632.5 |