一、主持科研项目情况: (1) 湘潭大学人才引进科研启动项目,耐高温聚酯的可控合成及性质研究,在研。 (2) 2021年度广州市科技计划-基础研究项目,三元共聚物的序列可控合成及性质研究,在研。 (3) 中国博士后科学基金第2批特别资助(站前),序列选择性开环共聚及机理研究,已结题。 (4) 中国博士后科学基金第66批面上资助(二等),醚酯共聚物的序列可控合成、表征及性质研究,已结题。 二、发表学术论文情况: (1) Zdovc, B.#; Li, H.#; Zhao, J.*; Pahovnik, D.; Žagar, E.*, Influence of Microstructure on the Elution Behavior of Gradient Copolymers in Different Modes of Liquid Interaction Chromatography. Anal. Chem. 2022, DOI: 10.1021/acs.analchem.2c00193. (2) He, G.; Li, H.*; Zhao, J.*, One-Step Sequence-Selective Synthesis of Block Copolyester from Mixed Phthalic Anhydride, Cyclohexene Oxide, and δ-Valerolactone. Macromol. Chem. Phys. 2021, 2100321. (3) Li, H.; He, G.; Chen, Y.; Zhao, J.*; Zhang, G., One-Step Approach to Polyester–Polyether Block Copolymers Using Highly Tunable Bicomponent Catalyst. ACS Macro Lett. 2019, 8, 973-978. (4) Li, H.; Luo, H.; Zhao, J.*; Zhang, G., Sequence-Selective Terpolymerization from Monomer Mixtures Using a Simple Organocatalyst. ACS Macro Lett. 2018, 7, 1420-1425. (5) Li, H.; Luo, H.; Zhao, J.*; Zhang, G., Well-Defined and Structurally Diverse Aromatic Alternating Polyesters Synthesized by Simple Phosphazene Catalysis. Macromolecules 2018, 51, 2247-2257. (6) Li, H.; Zhao, J.*; Zhang, G., Self-Buffering Organocatalysis Tailoring Alternating Polyester. ACS Macro Lett. 2017, 6, 1094-1098. (7) Li, H.; Liu, P.; Yuan, J.; Si, J.; Liu, Y.; Li, H.; Gao, Y.*, Thermo-Responsive Brush Copolymers by “Grafting through” Strategy Implemented on the Surface of the Macromonomer Micelles and Their High Emulsifying Performance. Macromol. Chem. Phys. 2017, 218, 1700131. (8) Li, H.; Miao, H.; Gao, Y.*; Li, H.; Chen, D., Efficient Synthesis of Narrowly Dispersed Amphiphilic Double-Brush Copolymers through the Polymerization Reaction of Macromonomer Micelle Emulsifiers at the Oil-Water Interface. Polym. Chem. 2016, 7, 4476-4485. (9) Li, H.; Yang, D.; Gao, Y.*; Li, H.; Xu, J.*, Dual Responsive Macroemulsion Stabilized by Y-Shaped Amphiphilic AB2 Miktoarm Star Copolymers. RSC Adv. 2015, 5, 96377-96386. (10) Zhang, B.; Li, H.; Luo, H.; Zhao, J.*, Ring-Opening Alternating Copolymerization of Epichlorohydrin and Cyclic Anhydrides Using Single- and Two-Component Metal-Free Catalysts. Eur. Polym. J. 2020, 134, 109820. (11) Yuan, J.; Li, H.; Gao, Y.*; Yang, D.; Liu, Y.*; Li, H.; Lu, S., Well-Defined Polyurethane-graft-Poly(N,N-dimethylacrylamide) Copolymer with a Controlled Graft Density and Grafted Chain Length: Synthesis and Its Application as a Pickering Emulsion. RSC Adv. 2016, 6, 58970-58978. 三、申请专利情况: (1) 赵俊鹏,李恒,何冠辰,张广照. 一种烯烃和环氧化物嵌段共聚的方法,中国发明专利,申请号:CN202110261669.6 (2) 赵俊鹏,李恒,张广照. 一种苯酐与环氧化合物共聚及序列控制方法,中国发明专利,授权号:ZL201910004325.X (3) 赵俊鹏,庞杰,李恒. 一种主链缩醛官能化共聚物的制备方法,中国发明专利,申请号:CN202110960870.3 (4) 高勇,袁俊,李恒,杨端光,黎华明. 一种聚氨酯接枝共聚物及其制备方法,中国发明专利,授权号:ZL201510575632.5 |